How to Balance Chemical Equations: A Complete GCSE Guide
Balancing chemical equations is one of the most fundamental skills in chemistry. It is based on the law of conservation of mass, which states that atoms cannot be created or destroyed during a chemical reaction. Our chemical equation balancer instantly balances equations for you and shows the step-by-step working, making it ideal for UK GCSE and A-Level Chemistry revision.
The Law of Conservation of Mass
Antoine Lavoisier established the law of conservation of mass in 1789. In any chemical reaction, the total mass of the reactants always equals the total mass of the products. This means the number of each type of atom must be the same on both sides of the chemical equation. When an equation satisfies this condition, it is said to be balanced.
For example, the unbalanced equation H2 + O2 → H2O shows 2 hydrogen atoms and 2 oxygen atoms on the left, but only 2 hydrogen atoms and 1 oxygen atom on the right. By adjusting coefficients to get 2H2 + O2 → 2H2O, we achieve 4 hydrogen atoms and 2 oxygen atoms on each side.
Step-by-Step Method for Balancing Equations
- Write the unbalanced equation with correct chemical formulas for all reactants and products.
- Count the atoms of each element on both sides of the arrow.
- Balance the most complex molecule first - usually the one with the most elements.
- Balance metals next, then non-metals, leaving hydrogen and oxygen until last.
- Adjust coefficients (never subscripts) until each element is balanced.
- Check your work by counting all atoms on both sides again.
- Add state symbols (s), (l), (g), (aq) if required.
Types of Chemical Reactions
Understanding the type of reaction helps predict products and balance equations more efficiently:
- Combustion: A fuel reacts with oxygen to produce carbon dioxide and water. Example: CH4 + 2O2 → CO2 + 2H2O
- Decomposition: One compound breaks down into simpler substances. Example: 2H2O2 → 2H2O + O2
- Neutralisation: An acid reacts with a base to form a salt and water. Example: HCl + NaOH → NaCl + H2O
- Displacement: A more reactive element displaces a less reactive one. Example: Fe + CuSO4 → FeSO4 + Cu
- Precipitation: Two solutions react to form an insoluble solid. Example: AgNO3 + NaCl → AgCl + NaNO3
- Redox: Simultaneous oxidation and reduction reactions occur with electron transfer.
State Symbols in Chemical Equations
State symbols provide important information about the physical state of each substance:
- (s) Solid - e.g. NaCl(s), Fe(s)
- (l) Liquid - e.g. H2O(l), Br2(l)
- (g) Gas - e.g. CO2(g), H2(g)
- (aq) Aqueous solution - e.g. HCl(aq), NaOH(aq)
State symbols are required for full marks in many GCSE and A-Level Chemistry examinations. They help describe the physical conditions under which the reaction takes place.
Reactants and Products
In a chemical equation, the substances on the left of the arrow are called reactants - these are the starting materials that are consumed during the reaction. The substances on the right are called products - these are the new substances formed. The arrow represents the chemical change taking place. In reversible reactions, a double arrow (⇌) is used to show that the reaction can proceed in both directions.
Coefficients and Mole Ratios
The coefficients in a balanced equation are the numbers placed in front of chemical formulas. They represent the relative number of moles (or molecules) of each substance involved. For instance, in 2H2 + O2 → 2H2O, the coefficient 2 in front of H2 means 2 moles of hydrogen react with 1 mole of oxygen to produce 2 moles of water. These ratios are essential for all stoichiometry calculations including theoretical yield, limiting reagent, and atom economy.
Atom Economy
Atom economy is a measure of how efficiently atoms from reactants end up in the desired product. It is calculated as:
Atom Economy = (Molecular mass of desired product / Total molecular mass of all products) × 100%
A high atom economy means fewer waste products and is an important consideration in green chemistry. The Haber process for ammonia synthesis (N2 + 3H2 → 2NH3) has a 100% atom economy as ammonia is the only product.
Important Industrial Reactions
Several industrial processes have balanced equations that are critical for GCSE and A-Level study:
- Haber Process: N2(g) + 3H2(g) ⇌ 2NH3(g) - produces ammonia for fertilisers
- Contact Process: 2SO2(g) + O2(g) ⇌ 2SO3(g) - makes sulfuric acid
- Thermal Decomposition of Limestone: CaCO3(s) → CaO(s) + CO2(g) - cement production
- Electrolysis of Brine: 2NaCl(aq) + 2H2O(l) → Cl2(g) + H2(g) + 2NaOH(aq) - chlor-alkali industry
- Blast Furnace: Fe2O3(s) + 3CO(g) → 2Fe(l) + 3CO2(g) - iron extraction